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I'm going with bug poop as well. I've found these on my car while parked outside less than 30 mins. Given the spot I was parked at there really is no other explanation. You have to get them off quick! I've had a couple that were left to fester for a while and experienced the same issue you describe, a yellowish spot about 1/4" in diameter on my white paint. My car is Opti-coated and while regular washing would remove the material in question the tinted spot remained. Clay bar helped fade it to almost unnoticeable. Over time they have either faded out or I just plain forgot exactly where to look for them.
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